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钱辉
有机化学，青年研究员，博士生导师
电子邮箱：qian_hui@fudan.edu.cn
办公地点：遗传楼412室
学习工作经历
研究兴趣
代表性论文及专著
获奖情况
小组成员
2007.08 – 2011.06 扬州大学化学化工学院，获得工学学士学位
2011.08 – 2015.08 香港科技大学化学系，获得理学博士学位
2016.10起 复旦大学化学系青年研究员
不对称催化
联烯的合成及其在合成中的应用
二氧化碳在有机合成中的应用
药物化学
Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids.
Wang, H.1; Luo, H.1; Zhang, Z.-M.1; Zheng, W.-F.; Yin, Y.; Qian, H.*; Zhang, J.*; Ma, S.* J. Am. Chem. Soc.2020, ASAP.
Rh-Catalyzed Reaction of Propargylic Alcohols with Aryl Boronic Acids-Switch from β-OH Elimination to Protodemetalation.
Wang, W.; Qian, H.*; Ma, S.* Chin. J. Chem.2020, 38, 331-345. (Breaking Report)
Palladium-Catalyzed Suzuki Coupling of Propargylic Alcohols with Boronic Acids under Ambient Conditions.
Qin, A.; Qian, H.; Chen, Q.*; Ma, S.* Chin. J. Chem. 2020, 38, 372-382.
Tetrasubstituted Allenes via the Palladium-Catalysed Kinetic Resolution of Propargylic Alcohols Using a Supporting Ligand.
Zheng, W.-F.; Zhang, W.; Huang, C.; Wu, P.; Qian, H.*; Wang, L.; Guo, Y.-L.*; Ma, S.* Nat. Catal.2019, 2, 997-1005.
Palladium-Catalyzed Desulfitative Cross-Coupling Reaction of Sodium Sulfinates with Propargylic Carbonates.
Qin, A.; Zhu, G.; Chen, Q.*; Qian, H.*; Ma, S.* Adv. Synth. Catal.2019, 361, 4656-4660. (VIP)
Identification of HSP90 as a Direct Target of Artemisinin for Its Anti-inflammatory Activity via Quantitative Chemical Proteomics.
Wu, G.; Cheng, B.; Qian, H.; Ma, S.; Chen, Q.* Org. Biomol. Chem.2019, 17, 6854-6859.Catalytic Selective Oxidative Coupling of Secondary N-Alkylanilines: An Approach to Azoxyarene.
Ke, L.; Zhu, G.; Qian, H.; Xiang, G.; Chen, Q.*; Chen, Z.* Org. Lett.2019, 21, 4008-4013.Hydroxy Group-Enabled Highly Regio- and Stereo-selective Hydrocarboxylation of Alkynes.
Huang, C.; Qian, H.; Zhang, W.*; Ma, S.* Chem. Sci. 2019, 10, 5505-5512.
Efficient Synthesis of Tetrasubstituted 2,3-Allenoates and Preliminary Studies on Bioactivities.
Yao, Y.; Zhu, G.; Chen, Q.*; Qian, H.*; Ma, S.* Org. Chem. Front.2019, 6, 304-308.
Tri(o-tolyl)phosphine for Highly Efficient Suzuki Coupling of Propargylic Carbonates with Boronic Acids
Xiao, J.; Luo, H.; Huang, S.; Qian, H.*; Ma, S.* Chem. Commun.2018, 54, 10451-10454.
2,3-Allenoic Acids via Palladium-Catalyzed Carboxylation of Propargylic Alcohols Zheng, W.-F.;
Zhang, W.; Huang, J.; Yu, Y.; Qian, H.*; Ma, S.* Org. Chem. Front.2018, 5, 1900-1904.
Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium Ring Lactams.
Zhao, W.1; Qian, H.1; Li, Z.*; Sun, J.* (1: equal contribution) Angew. Chem., Int. Ed.2015, 54, 10005-10008.Organocatalytic Enantio- and Diastereoselective Synthesis of 1,2-Dihydronaphthalenes from Isobenzopyrylium Ions.
Qian, H.; Zhao, W.; Wang, Z.; Sun, J.* J. Am. Chem. Soc.2015, 137, 560-563.Siloxy Alkynes in Annulation Reactions.
Qian, H.; Zhao, W.; Sun, J.* Chem. Rec. 2014, 14, 1070-1085.Organocatalytic Enantio- and Diastereoselective Assembly of Thiazolidine Scaffolds by Formal [3+2] Annulation.
Qian, H.; Sun, J.* Asian J. Org. Chem. 2014, 3, 387-390.Multi-targeted organometallic ruthenium(II)-arene anticncer complexes bearing inhibitors of poly(ADP-ribose) polymerase-1: A strategy to improve cytotoxicity.
Wang, Z.; Qian, H.; Yiu, S.-M.; Sun, J.; Zhu, G.* J. Inorg. Biochem. 2014, 131, 47-55.Platinated benzonaphthyridone is a stronger inhibitor of poly(ADP-ribose) polymerase-1 and a more potent anticancer agen than is the parent inhibitor.
Wang, B.; Qian, H.; Yiu, S.-M.; Sun, J.; Zhu, G.* Eur. J. Med. Chem. 2014, 71, 366-373.Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes.
Qian, H.; Yu, X.; Zhang, J.*; Sun, J.* J. Am. Chem. Soc.2013, 135, 18020-18023.Stereoselective Synthesis of Aminoindanols via An Efficient Cascade aza-Michael/Aldol Reaction.
Qian, H.; Zhao, W.; Sung, H. H.-Y.; Williams, I. D.; Sun, J.* Chem. Commun.2013, 49, 4361.
2010年 国家奖学金
2010年 江苏省优秀学生干部
2014年 Young Scientist Award（香港科技大学）
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